This has to do with Microsoft Outlook and Exchange mail software, please see the following documents:
- How to Prevent Winmail.dat Attachments from Being Sent in Outlook:
http://email.about.com/od/outlooktips/qt/Prevent_Winmail_dat_Attachments_from_Being_Sent_in_Outlook.htm - Disabe Winmail.dat Stubbornly Going to Recipients No Matter the Default:
http://email.about.com/od/outlooktips/ss/wt121705a.htm